Voltammetric lability of multiligand complexes : the case of ML2

J. Puy, J. Cecilia, J. Galceran, R.M. Town, H.P. van Leeuwen

Research output: Contribution to journalArticleAcademicpeer-review

24 Citations (Scopus)

Abstract

The voltammetric lability of a complex system, where a metal ion M and a ligand L form the species ML and ML2, is examined. Together with the rigorous numerical simulation of the problem, two limiting cases are analysed for the overall process ML2 ¿ M: (i) the most common case for aqueous complexes, where ML ¿ M is the kinetically limiting step and (ii) the case where ML2 ¿ ML is limiting. In both cases, analytical expressions for the lability criteria are provided which show good agreement with the results obtained from the rigorous numerical simulation of the problem.
Original languageEnglish
Pages (from-to)121-132
JournalJournal of Electroanalytical Chemistry
Volume571
Issue number2
DOIs
Publication statusPublished - 2004

Keywords

  • adsorption phenomena
  • systems
  • currents

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