Tuning the Electronic Communication between Redox Centers Bound to Insulating Surfaces

D. Zigah; C. Herrier; L.M.W. Scheres; M. Giesbers; B. Fabre; P. Hapiot; H. Zuilhof

doi:10.1002/anie.200906924

Tuning the Electronic Communication between Redox Centers Bound to Insulating Surfaces

D. Zigah, C. Herrier, L.M.W. Scheres, M. Giesbers, B. Fabre, P. Hapiot, H. Zuilhof

Research output: Contribution to journal › Article › Academic › peer-review

54 Citations (Scopus)

Abstract

Controlling communication: The electronic communication between ferrocenyl centers bound to insulating silicon surfaces can be efficiently controlled; scanning electrochemical microscopy (SECM) shows that both the surface coverage of the electroactive units and the nature of the redox mediator allow for this control. The lateral charge propagation can be precisely tuned from an extremely slow to a very fast process

Original language	English
Pages (from-to)	3157-3160
Journal	Angewandte Chemie-International Edition
Volume	49
Issue number	18
DOIs	https://doi.org/10.1002/anie.200906924
Publication status	Published - 2010

Keywords

scanning electrochemical microscopy
organic monolayers
ferrocene derivatives
active dendrimers
si(111) surfaces
visible-light
logic gates
silicon
attachment
alkyl

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10.1002/anie.200906924

Cite this

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title = "Tuning the Electronic Communication between Redox Centers Bound to Insulating Surfaces",

abstract = "Controlling communication: The electronic communication between ferrocenyl centers bound to insulating silicon surfaces can be efficiently controlled; scanning electrochemical microscopy (SECM) shows that both the surface coverage of the electroactive units and the nature of the redox mediator allow for this control. The lateral charge propagation can be precisely tuned from an extremely slow to a very fast process",

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AU - Fabre, B.

AU - Hapiot, P.

AU - Zuilhof, H.

PY - 2010

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AB - Controlling communication: The electronic communication between ferrocenyl centers bound to insulating silicon surfaces can be efficiently controlled; scanning electrochemical microscopy (SECM) shows that both the surface coverage of the electroactive units and the nature of the redox mediator allow for this control. The lateral charge propagation can be precisely tuned from an extremely slow to a very fast process

KW - scanning electrochemical microscopy

KW - organic monolayers

KW - ferrocene derivatives

KW - active dendrimers

KW - si(111) surfaces

KW - visible-light

KW - logic gates

KW - silicon

KW - attachment

KW - alkyl

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DO - 10.1002/anie.200906924

M3 - Article

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ER -

Tuning the Electronic Communication between Redox Centers Bound to Insulating Surfaces

Abstract

Keywords

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