Tuning the Electronic Communication between Redox Centers Bound to Insulating Surfaces

D. Zigah, C. Herrier, L.M.W. Scheres, M. Giesbers, B. Fabre, P. Hapiot, H. Zuilhof

Research output: Contribution to journalArticleAcademicpeer-review

52 Citations (Scopus)

Abstract

Controlling communication: The electronic communication between ferrocenyl centers bound to insulating silicon surfaces can be efficiently controlled; scanning electrochemical microscopy (SECM) shows that both the surface coverage of the electroactive units and the nature of the redox mediator allow for this control. The lateral charge propagation can be precisely tuned from an extremely slow to a very fast process
Original languageEnglish
Pages (from-to)3157-3160
JournalAngewandte Chemie-International Edition
Volume49
Issue number18
DOIs
Publication statusPublished - 2010

Keywords

  • scanning electrochemical microscopy
  • organic monolayers
  • ferrocene derivatives
  • active dendrimers
  • si(111) surfaces
  • visible-light
  • logic gates
  • silicon
  • attachment
  • alkyl

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