The Future of Ethenolysis in Biobased Chemistry

Jurjen Spekreijse, Johan P.M. Sanders, Johannes H. Bitter, Elinor L. Scott*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

23 Citations (Scopus)

Abstract

The desire to utilise biobased feedstocks and develop more sustainable chemistry poses new challenges in catalysis. A synthetically useful catalytic conversion is ethenolysis, a cross metathesis reaction with ethylene. In this Review, the state of the art of ethenolysis in biobased chemistry was extensively examined using methyl oleate as a model compound for fatty acids. Allied to this, the ethenolysis of fatty acid, polymers and more challenging substrates are reviewed. To determine the limiting factors for the application of ethenolysis on biomass, the influence of reaction parameters were investigated and the bottlenecks for reaching high turnover numbers identified.
Original languageEnglish
Pages (from-to)470-482
JournalChemSusChem
Volume10
Issue number3
DOIs
Publication statusPublished - 2017

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    Spekreijse, J., Sanders, J. P. M., Bitter, J. H., & Scott, E. L. (2017). The Future of Ethenolysis in Biobased Chemistry. ChemSusChem, 10(3), 470-482. https://doi.org/10.1002/cssc.201601256