Synthesis of 4-functionalized terdendate pyridine-based ligands

T. Vermonden, D. Branowska, A.T.M. Marcelis, E.J.R. Sudhölter

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Abstract

Four different 4-functionalised pyridine-based ligands were synthesized with aminomethyl, oxazolinyl, pyrazolyl and methylimidazolyl groups at the 2- and 6-position. The nitrogens of these groups together with the pyridine nitrogen can act as terdendate ligands for metal ions. Synthetic handles on the 4-position of the pyridine :group were introduced via ether or ester bonds leading to monofunctional, bifunctional and amphiphilic ligands. (C) 2003 Published by Fisevier Science Ltd.
Original languageEnglish
Pages (from-to)5039-5045
JournalTetrahedron
Volume59
DOIs
Publication statusPublished - 2003

Keywords

  • ruthenium(ii) complexes
  • coordination polymers
  • oligopyridines
  • lanthanide
  • chemistry
  • analogs

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    Vermonden, T., Branowska, D., Marcelis, A. T. M., & Sudhölter, E. J. R. (2003). Synthesis of 4-functionalized terdendate pyridine-based ligands. Tetrahedron, 59, 5039-5045. https://doi.org/10.1016/S0040-4020(03)00753-1