Selective preparation of terminal alkenes from aliphatic carboxylic acids by a palladium-catalysed decarbonylation-eliminiation reaction

J.E.L. le Notre; E.L. Scott; M.C.R. Franssen; J.P.M. Sanders

doi:10.1016/j.tetlet.2010.05.018

Selective preparation of terminal alkenes from aliphatic carboxylic acids by a palladium-catalysed decarbonylation-eliminiation reaction

J.E.L. le Notre, E.L. Scott, M.C.R. Franssen, J.P.M. Sanders

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Trialkylamines were used as additives in the decarbonylation–elimination reaction catalysed by the combination of palladium(II) chloride and DPE-Phos. Aliphatic carboxylic acids were transformed at relatively low temperature into terminal alkenes in high yield and high selectivity, without the need for distillation, thereby avoiding isomerisation

Original language	English
Pages (from-to)	3712-3715
Journal	Tetrahedron Letters
Volume	51
Issue number	29
DOIs	https://doi.org/10.1016/j.tetlet.2010.05.018
Publication status	Published - 2010

Keywords

biodiesel production
stearic-acid
fatty-acids
deoxygenation
oil
decarboxylation
telomerization
conversion
butadiene
chemicals

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10.1016/j.tetlet.2010.05.018

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title = "Selective preparation of terminal alkenes from aliphatic carboxylic acids by a palladium-catalysed decarbonylation-eliminiation reaction",

abstract = "Trialkylamines were used as additives in the decarbonylation–elimination reaction catalysed by the combination of palladium(II) chloride and DPE-Phos. Aliphatic carboxylic acids were transformed at relatively low temperature into terminal alkenes in high yield and high selectivity, without the need for distillation, thereby avoiding isomerisation",

keywords = "biodiesel production, stearic-acid, fatty-acids, deoxygenation, oil, decarboxylation, telomerization, conversion, butadiene, chemicals",

author = "{le Notre}, J.E.L. and E.L. Scott and M.C.R. Franssen and J.P.M. Sanders",

year = "2010",

doi = "10.1016/j.tetlet.2010.05.018",

language = "English",

volume = "51",

pages = "3712--3715",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "29",

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T1 - Selective preparation of terminal alkenes from aliphatic carboxylic acids by a palladium-catalysed decarbonylation-eliminiation reaction

AU - le Notre, J.E.L.

AU - Scott, E.L.

AU - Franssen, M.C.R.

AU - Sanders, J.P.M.

PY - 2010

Y1 - 2010

N2 - Trialkylamines were used as additives in the decarbonylation–elimination reaction catalysed by the combination of palladium(II) chloride and DPE-Phos. Aliphatic carboxylic acids were transformed at relatively low temperature into terminal alkenes in high yield and high selectivity, without the need for distillation, thereby avoiding isomerisation

AB - Trialkylamines were used as additives in the decarbonylation–elimination reaction catalysed by the combination of palladium(II) chloride and DPE-Phos. Aliphatic carboxylic acids were transformed at relatively low temperature into terminal alkenes in high yield and high selectivity, without the need for distillation, thereby avoiding isomerisation

KW - biodiesel production

KW - stearic-acid

KW - fatty-acids

KW - deoxygenation

KW - oil

KW - decarboxylation

KW - telomerization

KW - conversion

KW - butadiene

KW - chemicals

U2 - 10.1016/j.tetlet.2010.05.018

DO - 10.1016/j.tetlet.2010.05.018

M3 - Article

SN - 0040-4039

VL - 51

SP - 3712

EP - 3715

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 29

ER -

Selective preparation of terminal alkenes from aliphatic carboxylic acids by a palladium-catalysed decarbonylation-eliminiation reaction

Abstract

Keywords

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