Selective precipitation of Cu from Zn in a pS controlled continuously stirred tank reactor

R.M. Sampaio, R.A. Timmers, Y. Xu, K.J. Keesman, P.N.L. Lens

Research output: Contribution to journalArticleAcademicpeer-review

74 Citations (Scopus)

Abstract

Copper was continuously and selectively precipitated with Na2S to concentrations below 0.3 ppb from water containing around 600 ppm of both Cu and Zn in a Continuously Stirred Tank Reactor. The pH was controlled at 3 and the pS at 25 (pS = ¿log(S2¿)) by means of an Ag2S sulfide selective electrode. Copper's recovery and purity were about 100%, whereas the total soluble sulfide concentration was below 0.02 ppm. X-ray diffraction (XRD) analysis showed that copper precipitated as hexagonal CuS (covellite). The mode of the particle size distribution (PSD) of the CuS precipitates was around 36 ¿m. The PSD increased by high pS values and by the presence of Zn. Depending on the turbulence, the CuS precipitates can grow up to 200 ¿m or fragment in particles smaller than 3 ¿m in a few seconds. Zn precipitation with Na2S at pH 3 and 4, in batch, always lead to Zn concentrations above 1 ppm. Zn precipitated as cubic ZnS (spharelite)
Original languageEnglish
Pages (from-to)256-265
JournalJournal of Hazardous Materials
Volume165
Issue number1-3
DOIs
Publication statusPublished - 2009

Keywords

  • acid-mine drainage
  • sulfate-reducing bacteria
  • heavy-metal precipitation
  • sulfide precipitation
  • ion-exchange
  • copper speciation
  • sphalerite zns
  • removal
  • water
  • separation

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