Ruthenium-catalyzed nucleophilic fluorination of halobenzenes

Andrey I. Konovalov, Evgeniya O. Gorbacheva, Fedor M. Miloserdov, Vladimir V. Grushin*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

39 Citations (Scopus)

Abstract

The first π-coordination-catalyzed nucleophilic fluorination of unactivated aryl halides has been demonstrated. Chlorobenzene reacts with alkali metal fluorides (CsF, KF) in the presence of a Cp∗Ru catalyst at 120-180°C to give fluorobenzene.

Original languageEnglish
Pages (from-to)13527-13530
Number of pages4
JournalChemical Communications
Volume51
Issue number70
DOIs
Publication statusPublished - 15 Jul 2015
Externally publishedYes

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