Retention-time database of 126 polybrominated diphenyl ether congeners and two Bromkal technical mixtures on seven capillary gas chromatography columns

P. Korytar; A. Covaci; J. de Boer; A. Gelbin; U.A.Th. Brinkman

doi:10.1016/j.chroma.2004.12.059

Retention-time database of 126 polybrominated diphenyl ether congeners and two Bromkal technical mixtures on seven capillary gas chromatography columns

P. Korytar, A. Covaci, J. de Boer, A. Gelbin, U.A.Th. Brinkman

Research output: Contribution to journal › Article › Academic › peer-review

137 Citations (Scopus)

Abstract

The elution order of 126 polybrominated diphenyl ethers (PBDE) was determined for seven different gas chromatographic (GC) stationary phases. The resulting database facilitates selection of the most suitable GC columns for developing a quantitative, congener-specific BDE analysis and the testing of retention prediction algorithms based on structure relationships of GC phases and congener substitution patterns. In addition, co-elutions of the principal BDE congeners with other BDEs and/or with other brominated flame retardants were investigated and, as an application, the composition of two Bromkal mixtures (70-5DE and 79-8DE) was studied. (C) 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	239-249
Journal	Journal of Chromatography. A, Including electrophoresis and other separation methods
Volume	1065
Issue number	2
DOIs	https://doi.org/10.1016/j.chroma.2004.12.059
Publication status	Published - 2005

Keywords

brominated flame retardants
carp cyprinus-carpio
samples
pbdes
blood
identification
debromination

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10.1016/j.chroma.2004.12.059

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Korytar, P., Covaci, A., de Boer, J., Gelbin, A., & Brinkman, U. A. T. (2005). Retention-time database of 126 polybrominated diphenyl ether congeners and two Bromkal technical mixtures on seven capillary gas chromatography columns. Journal of Chromatography. A, Including electrophoresis and other separation methods, 1065(2), 239-249. https://doi.org/10.1016/j.chroma.2004.12.059

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title = "Retention-time database of 126 polybrominated diphenyl ether congeners and two Bromkal technical mixtures on seven capillary gas chromatography columns",

abstract = "The elution order of 126 polybrominated diphenyl ethers (PBDE) was determined for seven different gas chromatographic (GC) stationary phases. The resulting database facilitates selection of the most suitable GC columns for developing a quantitative, congener-specific BDE analysis and the testing of retention prediction algorithms based on structure relationships of GC phases and congener substitution patterns. In addition, co-elutions of the principal BDE congeners with other BDEs and/or with other brominated flame retardants were investigated and, as an application, the composition of two Bromkal mixtures (70-5DE and 79-8DE) was studied. (C) 2004 Elsevier B.V. All rights reserved.",

keywords = "brominated flame retardants, carp cyprinus-carpio, samples, pbdes, blood, identification, debromination",

author = "P. Korytar and A. Covaci and {de Boer}, J. and A. Gelbin and U.A.Th. Brinkman",

year = "2005",

doi = "10.1016/j.chroma.2004.12.059",

language = "English",

volume = "1065",

pages = "239--249",

journal = "Journal of Chromatography. A, Including electrophoresis and other separation methods",

issn = "0021-9673",

publisher = "Elsevier",

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}

Korytar, P, Covaci, A, de Boer, J, Gelbin, A & Brinkman, UAT 2005, 'Retention-time database of 126 polybrominated diphenyl ether congeners and two Bromkal technical mixtures on seven capillary gas chromatography columns', Journal of Chromatography. A, Including electrophoresis and other separation methods, vol. 1065, no. 2, pp. 239-249. https://doi.org/10.1016/j.chroma.2004.12.059

Retention-time database of 126 polybrominated diphenyl ether congeners and two Bromkal technical mixtures on seven capillary gas chromatography columns. / Korytar, P.; Covaci, A.; de Boer, J. et al.
In: Journal of Chromatography. A, Including electrophoresis and other separation methods, Vol. 1065, No. 2, 2005, p. 239-249.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Retention-time database of 126 polybrominated diphenyl ether congeners and two Bromkal technical mixtures on seven capillary gas chromatography columns

AU - Korytar, P.

AU - Covaci, A.

AU - de Boer, J.

AU - Gelbin, A.

AU - Brinkman, U.A.Th.

PY - 2005

Y1 - 2005

N2 - The elution order of 126 polybrominated diphenyl ethers (PBDE) was determined for seven different gas chromatographic (GC) stationary phases. The resulting database facilitates selection of the most suitable GC columns for developing a quantitative, congener-specific BDE analysis and the testing of retention prediction algorithms based on structure relationships of GC phases and congener substitution patterns. In addition, co-elutions of the principal BDE congeners with other BDEs and/or with other brominated flame retardants were investigated and, as an application, the composition of two Bromkal mixtures (70-5DE and 79-8DE) was studied. (C) 2004 Elsevier B.V. All rights reserved.

AB - The elution order of 126 polybrominated diphenyl ethers (PBDE) was determined for seven different gas chromatographic (GC) stationary phases. The resulting database facilitates selection of the most suitable GC columns for developing a quantitative, congener-specific BDE analysis and the testing of retention prediction algorithms based on structure relationships of GC phases and congener substitution patterns. In addition, co-elutions of the principal BDE congeners with other BDEs and/or with other brominated flame retardants were investigated and, as an application, the composition of two Bromkal mixtures (70-5DE and 79-8DE) was studied. (C) 2004 Elsevier B.V. All rights reserved.

KW - brominated flame retardants

KW - carp cyprinus-carpio

KW - samples

KW - pbdes

KW - blood

KW - identification

KW - debromination

U2 - 10.1016/j.chroma.2004.12.059

DO - 10.1016/j.chroma.2004.12.059

M3 - Article

SN - 0021-9673

VL - 1065

SP - 239

EP - 249

JO - Journal of Chromatography. A, Including electrophoresis and other separation methods

JF - Journal of Chromatography. A, Including electrophoresis and other separation methods

IS - 2

ER -

Retention-time database of 126 polybrominated diphenyl ether congeners and two Bromkal technical mixtures on seven capillary gas chromatography columns

Abstract

Keywords

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