TY - JOUR
T1 - Recovery of calcium phosphate granules from black water using a hybrid upflow anaerobic sludge bed and gas-lift reactor
AU - Cunha, Jorge Ricardo
AU - Schott, Chris
AU - van der Weijden, Renata D.
AU - Leal, Lucía Hernández
AU - Zeeman, Grietje
AU - Buisman, Cees
PY - 2019/11
Y1 - 2019/11
N2 - Adding calcium during anaerobic digestion of vacuum collected black water (BW) in an up-flow anaerobic sludge bed (UASB) reactor increased the retention of total phosphorus (P) in the reactor from 51% to 87%. However, the insufficient mixing in the reactor caused cementation and relatively high content of organics in the recovered calcium phosphate (CaP) granules, limiting the P recovery. In this study, the UASB reactor was mixed with an internal gas-lift (UASB-GL) to prevent cementation and to enhance the P content in CaP granules. The novel UASB-GL reactor operated for 300 days, treating concentrated BW. At steady state, the removal of total COD and P was 92% and 90%, respectively. The gas injection created a sludge bed with an average total suspended solids concentration of 73 ± 16 g/L at the bottom and 31 ± 5 g/L at the top of the reactor. The concentration of solid P at the bottom of the reactor was 4.58 ± 1.34 gP/L, while at the top a much lower concentration was obtained (0.75 ± 0.32 gP/L). 89% of the CaP granules was found at the bottom of the reactor. The harvested CaP granules (>0.4 mm diameter) contained on average 7.8 ± 0.6 wt% of P. A potential recovery of 57% of P in BW as CaP granules was calculated, considering actual application of the UASB-GL reactor in source separated sanitation.
AB - Adding calcium during anaerobic digestion of vacuum collected black water (BW) in an up-flow anaerobic sludge bed (UASB) reactor increased the retention of total phosphorus (P) in the reactor from 51% to 87%. However, the insufficient mixing in the reactor caused cementation and relatively high content of organics in the recovered calcium phosphate (CaP) granules, limiting the P recovery. In this study, the UASB reactor was mixed with an internal gas-lift (UASB-GL) to prevent cementation and to enhance the P content in CaP granules. The novel UASB-GL reactor operated for 300 days, treating concentrated BW. At steady state, the removal of total COD and P was 92% and 90%, respectively. The gas injection created a sludge bed with an average total suspended solids concentration of 73 ± 16 g/L at the bottom and 31 ± 5 g/L at the top of the reactor. The concentration of solid P at the bottom of the reactor was 4.58 ± 1.34 gP/L, while at the top a much lower concentration was obtained (0.75 ± 0.32 gP/L). 89% of the CaP granules was found at the bottom of the reactor. The harvested CaP granules (>0.4 mm diameter) contained on average 7.8 ± 0.6 wt% of P. A potential recovery of 57% of P in BW as CaP granules was calculated, considering actual application of the UASB-GL reactor in source separated sanitation.
KW - Anaerobic treatment
KW - Calcium phosphate precipitation
KW - Crystallisation
KW - Granulation
KW - Methane
U2 - 10.1016/j.envres.2019.108671
DO - 10.1016/j.envres.2019.108671
M3 - Article
AN - SCOPUS:85071974087
SN - 0013-9351
VL - 178
JO - Environmental Research
JF - Environmental Research
M1 - 108671
ER -