Rapid detection of pesticides not amenable to multi-residue methods by flow injection-tandem mass spectrometry

J.G.J. Mol; R.C.J. van Dam

doi:10.1007/s00216-014-7644-8

Rapid detection of pesticides not amenable to multi-residue methods by flow injection-tandem mass spectrometry

J.G.J. Mol, R.C.J. van Dam

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50 Citations (Scopus)

Abstract

Flow injection combined with tandem mass spectrometry (MS/MS) was investigated for the rapid detection of highly polar pesticides that are not amenable to multi-residue methods because they do not partition into organic solvents and require dedicated chromatographic conditions. The pesticides included in this study were amitrole, chlormequat, cyromazine, daminozide, diquat, ethephon, fosetyl-Al, glufosinate, glyphosate and its metabolite aminomethylphosphonic acid, maleic hydrazide, mepiquat and paraquat. The composition of the flow-injection solvent was optimized to achieve maximum MS/MS sensitivity. Instrumental limits of detection varied between

Original language	English
Pages (from-to)	6817-6825
Journal	Analytical and Bioanalytical Chemistry
Volume	406
Issue number	27
DOIs	https://doi.org/10.1007/s00216-014-7644-8
Publication status	Published - 2014

Keywords

liquid-chromatography
aminomethylphosphonic acid
quantitative-analysis
sample preparation
maleic hydrazide
lc-ms/ms
glyphosate
cereals
vegetables
dilution

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10.1007/s00216-014-7644-8

Methodeontwikkeling, accreditatiebehoud en surveys milieucontaminanten en gewasbeschermingsmiddelen t.b.v. WOT (WOT-02-001-017, WOT-02-001-046)
Rijk, J. (Project Leader)
1/01/08 → 31/12/25
Project: LVVN project

Cite this

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title = "Rapid detection of pesticides not amenable to multi-residue methods by flow injection-tandem mass spectrometry",

abstract = "Flow injection combined with tandem mass spectrometry (MS/MS) was investigated for the rapid detection of highly polar pesticides that are not amenable to multi-residue methods because they do not partition into organic solvents and require dedicated chromatographic conditions. The pesticides included in this study were amitrole, chlormequat, cyromazine, daminozide, diquat, ethephon, fosetyl-Al, glufosinate, glyphosate and its metabolite aminomethylphosphonic acid, maleic hydrazide, mepiquat and paraquat. The composition of the flow-injection solvent was optimized to achieve maximum MS/MS sensitivity. Instrumental limits of detection varied between",

keywords = "liquid-chromatography, aminomethylphosphonic acid, quantitative-analysis, sample preparation, maleic hydrazide, lc-ms/ms, glyphosate, cereals, vegetables, dilution",

author = "J.G.J. Mol and {van Dam}, R.C.J.",

year = "2014",

doi = "10.1007/s00216-014-7644-8",

language = "English",

volume = "406",

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journal = "Analytical and Bioanalytical Chemistry",

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T1 - Rapid detection of pesticides not amenable to multi-residue methods by flow injection-tandem mass spectrometry

AU - Mol, J.G.J.

AU - van Dam, R.C.J.

PY - 2014

Y1 - 2014

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AB - Flow injection combined with tandem mass spectrometry (MS/MS) was investigated for the rapid detection of highly polar pesticides that are not amenable to multi-residue methods because they do not partition into organic solvents and require dedicated chromatographic conditions. The pesticides included in this study were amitrole, chlormequat, cyromazine, daminozide, diquat, ethephon, fosetyl-Al, glufosinate, glyphosate and its metabolite aminomethylphosphonic acid, maleic hydrazide, mepiquat and paraquat. The composition of the flow-injection solvent was optimized to achieve maximum MS/MS sensitivity. Instrumental limits of detection varied between

KW - liquid-chromatography

KW - aminomethylphosphonic acid

KW - quantitative-analysis

KW - sample preparation

KW - maleic hydrazide

KW - lc-ms/ms

KW - glyphosate

KW - cereals

KW - vegetables

KW - dilution

U2 - 10.1007/s00216-014-7644-8

DO - 10.1007/s00216-014-7644-8

M3 - Article

SN - 1618-2642

VL - 406

SP - 6817

EP - 6825

JO - Analytical and Bioanalytical Chemistry

JF - Analytical and Bioanalytical Chemistry

IS - 27

ER -

Rapid detection of pesticides not amenable to multi-residue methods by flow injection-tandem mass spectrometry

Abstract

Keywords

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Projects

Methodeontwikkeling, accreditatiebehoud en surveys milieucontaminanten en gewasbeschermingsmiddelen t.b.v. WOT (WOT-02-001-017, WOT-02-001-046)

Cite this