Multi-responsive reversible gels based on charge-driven assembly

M. Lemmers; J.H.B. Sprakel; I.K. Voets; J. van der Gucht; M.A. Cohen Stuart

doi:10.1002/anie.200905515

Multi-responsive reversible gels based on charge-driven assembly

M. Lemmers, J.H.B. Sprakel, I.K. Voets, J. van der Gucht, M.A. Cohen Stuart

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Research output: Contribution to journal › Article › Academic › peer-review

135 Citations (Scopus)

Abstract

Linked in? Coassembly of an ABA triblock copolymer with charged end blocks and an oppositely charged polyelectrolyte yields gels that respond to changes in concentration, temperature, ionic strength, pH value, and charge composition. Above the critical gel concentration, the triblock copolymers bridge micelles, forming a sample-spanning transient network of interconnected micelles

Original language	English
Pages (from-to)	708-711
Journal	Angewandte Chemie-International Edition
Volume	49
Issue number	4
DOIs	https://doi.org/10.1002/anie.200905515
Publication status	Published - 2010

Keywords

transfer radical polymerization
indirect fourier transformation
small-angle scattering
rheological properties
block-copolymers
methyl-methacrylate
chain-length
polyelectrolyte
micelles
polymers

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10.1002/anie.200905515

Cite this

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title = "Multi-responsive reversible gels based on charge-driven assembly",

abstract = "Linked in? Coassembly of an ABA triblock copolymer with charged end blocks and an oppositely charged polyelectrolyte yields gels that respond to changes in concentration, temperature, ionic strength, pH value, and charge composition. Above the critical gel concentration, the triblock copolymers bridge micelles, forming a sample-spanning transient network of interconnected micelles",

keywords = "transfer radical polymerization, indirect fourier transformation, small-angle scattering, rheological properties, block-copolymers, methyl-methacrylate, chain-length, polyelectrolyte, micelles, polymers",

author = "M. Lemmers and J.H.B. Sprakel and I.K. Voets and {van der Gucht}, J. and {Cohen Stuart}, M.A.",

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T1 - Multi-responsive reversible gels based on charge-driven assembly

AU - Lemmers, M.

AU - Sprakel, J.H.B.

AU - Voets, I.K.

AU - van der Gucht, J.

AU - Cohen Stuart, M.A.

PY - 2010

Y1 - 2010

N2 - Linked in? Coassembly of an ABA triblock copolymer with charged end blocks and an oppositely charged polyelectrolyte yields gels that respond to changes in concentration, temperature, ionic strength, pH value, and charge composition. Above the critical gel concentration, the triblock copolymers bridge micelles, forming a sample-spanning transient network of interconnected micelles

AB - Linked in? Coassembly of an ABA triblock copolymer with charged end blocks and an oppositely charged polyelectrolyte yields gels that respond to changes in concentration, temperature, ionic strength, pH value, and charge composition. Above the critical gel concentration, the triblock copolymers bridge micelles, forming a sample-spanning transient network of interconnected micelles

KW - transfer radical polymerization

KW - indirect fourier transformation

KW - small-angle scattering

KW - rheological properties

KW - block-copolymers

KW - methyl-methacrylate

KW - chain-length

KW - polyelectrolyte

KW - micelles

KW - polymers

U2 - 10.1002/anie.200905515

DO - 10.1002/anie.200905515

M3 - Article

SN - 1433-7851

VL - 49

SP - 708

EP - 711

JO - Angewandte Chemie-International Edition

JF - Angewandte Chemie-International Edition

IS - 4

ER -

Multi-responsive reversible gels based on charge-driven assembly

Abstract

Keywords

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