This study's aim was to evaluate the effect of processing conditions on the morphology and enzymatic degradation of 50/50 (w/w) thermoplastic starch-polycaprolactone blends. The blends, produced from native potato starch, glycerol, and polycaprolactone in a melt mixer using different mixing speeds and temperatures, were cocontinuous, and the blends were very homogeneous. Enzymatic hydrolysis was performed using Bacillus licheniformis alpha-amylase and Aspergillus niger glucoamylase on both milled and intact samples. The thin layer of polycaprolactone (≈ 5 μm) formed on the surface of the thermoplastic starch-polycaprolactone blends during compression molding strongly reduced the rate of enzymatic hydrolysis.
|Journal||Journal of Applied Polymer Science|
|Publication status||Published - 1999|
Vikman, M., Hulleman, S. H. D., van der Zee, M., Myllarinen, P., & Feil, H. (1999). Morphology and enzymatic degradation of thermoplastic starch-polycaprolactone blends. Journal of Applied Polymer Science, 74(11), 2594-2604. https://doi.org/10.1002/(sici)1097-4628(19991209)74:11<2594::aid-app5>3.0.co;2-r