Mechanochemical Immobilisation of Metathesis Catalysts in a Metal–Organic Framework

Jurjen Spekreijse; Lars Öhrström; Johan P.M. Sanders; Harry Bitter; Elinor L. Scott

doi:10.1002/chem.201602331

Mechanochemical Immobilisation of Metathesis Catalysts in a Metal–Organic Framework

Jurjen Spekreijse, Lars Öhrström, Johan P.M. Sanders, Harry Bitter, Elinor L. Scott^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

24 Citations (Scopus)

Abstract

A simple, one-step mechanochemical procedure for immobilisation of homogeneous metathesis catalysts in metal–organic frameworks was developed. Grinding MIL-101-NH₂(Al) with a Hoveyda–Grubbs second-generation catalyst resulted in a heterogeneous catalyst that is active for metathesis and one of the most stable immobilised metathesis catalysts. During the mechanochemical immobilisation the MIL-101-NH₂(Al) structure was partially converted to MIL-53-NH₂(Al). The Hoveyda–Grubbs catalyst entrapped in MIL-101-NH₂(Al) is responsible for the observed catalytic activity. The developed synthetic procedure was also successful for the immobilisation of a Zhan catalyst.

Original language	English
Pages (from-to)	15437-15443
Journal	Chemistry-A European Journal
Volume	22
Issue number	43
DOIs	https://doi.org/10.1002/chem.201602331
Publication status	Published - 2016

Keywords

heterogeneous catalysis
immobilization
mechanochemistry
metal–organic frameworks
metathesis

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title = "Mechanochemical Immobilisation of Metathesis Catalysts in a Metal–Organic Framework",

abstract = "A simple, one-step mechanochemical procedure for immobilisation of homogeneous metathesis catalysts in metal–organic frameworks was developed. Grinding MIL-101-NH2(Al) with a Hoveyda–Grubbs second-generation catalyst resulted in a heterogeneous catalyst that is active for metathesis and one of the most stable immobilised metathesis catalysts. During the mechanochemical immobilisation the MIL-101-NH2(Al) structure was partially converted to MIL-53-NH2(Al). The Hoveyda–Grubbs catalyst entrapped in MIL-101-NH2(Al) is responsible for the observed catalytic activity. The developed synthetic procedure was also successful for the immobilisation of a Zhan catalyst.",

keywords = "heterogeneous catalysis, immobilization, mechanochemistry, metal–organic frameworks, metathesis",

author = "Jurjen Spekreijse and Lars {\"O}hrstr{\"o}m and Sanders, \{Johan P.M.\} and Harry Bitter and Scott, \{Elinor L.\}",

year = "2016",

doi = "10.1002/chem.201602331",

language = "English",

volume = "22",

pages = "15437--15443",

journal = "Chemistry-A European Journal",

issn = "0947-6539",

publisher = "VCH",

number = "43",

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TY - JOUR

T1 - Mechanochemical Immobilisation of Metathesis Catalysts in a Metal–Organic Framework

AU - Spekreijse, Jurjen

AU - Öhrström, Lars

AU - Sanders, Johan P.M.

AU - Bitter, Harry

AU - Scott, Elinor L.

PY - 2016

Y1 - 2016

N2 - A simple, one-step mechanochemical procedure for immobilisation of homogeneous metathesis catalysts in metal–organic frameworks was developed. Grinding MIL-101-NH2(Al) with a Hoveyda–Grubbs second-generation catalyst resulted in a heterogeneous catalyst that is active for metathesis and one of the most stable immobilised metathesis catalysts. During the mechanochemical immobilisation the MIL-101-NH2(Al) structure was partially converted to MIL-53-NH2(Al). The Hoveyda–Grubbs catalyst entrapped in MIL-101-NH2(Al) is responsible for the observed catalytic activity. The developed synthetic procedure was also successful for the immobilisation of a Zhan catalyst.

AB - A simple, one-step mechanochemical procedure for immobilisation of homogeneous metathesis catalysts in metal–organic frameworks was developed. Grinding MIL-101-NH2(Al) with a Hoveyda–Grubbs second-generation catalyst resulted in a heterogeneous catalyst that is active for metathesis and one of the most stable immobilised metathesis catalysts. During the mechanochemical immobilisation the MIL-101-NH2(Al) structure was partially converted to MIL-53-NH2(Al). The Hoveyda–Grubbs catalyst entrapped in MIL-101-NH2(Al) is responsible for the observed catalytic activity. The developed synthetic procedure was also successful for the immobilisation of a Zhan catalyst.

KW - heterogeneous catalysis

KW - immobilization

KW - mechanochemistry

KW - metal–organic frameworks

KW - metathesis

U2 - 10.1002/chem.201602331

DO - 10.1002/chem.201602331

M3 - Article

AN - SCOPUS:84990250009

SN - 0947-6539

VL - 22

SP - 15437

EP - 15443

JO - Chemistry-A European Journal

JF - Chemistry-A European Journal

IS - 43

ER -

Mechanochemical Immobilisation of Metathesis Catalysts in a Metal–Organic Framework

Abstract

Keywords

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