Isohexide Derivatives from Renewable Resources as Chiral Building Blocks

J. Wu; P. Eduard; S. Thiyagarajan; J. van Haveren; D.S. van Es; C.E. Koning; M. Lutz; C. Fonesca Guerra

doi:10.1002/cssc.201100076

Isohexide Derivatives from Renewable Resources as Chiral Building Blocks

J. Wu, P. Eduard, S. Thiyagarajan, J. van Haveren, D.S. van Es, C.E. Koning, M. Lutz, C. Fonesca Guerra

Research output: Contribution to journal › Article › Academic › peer-review

60 Citations (Scopus)

Abstract

A new family of C2/C5 carbon-extended isohexide derivatives is synthesized in a stereo-controlled manner with high purity and good yield. These chiral and rigid biobased building blocks can be widely applied: in pharmaceuticals, cholesteric liquid crystals, and as building blocks for high-performance polymers. The isoidide-based diacid is a potential renewable alternative to terephthalic acid.

Original language	English
Pages (from-to)	599-603
Journal	ChemSusChem
Volume	4
Issue number	5
DOIs	https://doi.org/10.1002/cssc.201100076
Publication status	Published - 2011

Keywords

asymmetric transfer hydrogenation
molecular structure
terephthalic acid
crystal-structure
isosorbide
chemistry
polymers
ligands
polyurethanes
isomannide

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title = "Isohexide Derivatives from Renewable Resources as Chiral Building Blocks",

abstract = "A new family of C2/C5 carbon-extended isohexide derivatives is synthesized in a stereo-controlled manner with high purity and good yield. These chiral and rigid biobased building blocks can be widely applied: in pharmaceuticals, cholesteric liquid crystals, and as building blocks for high-performance polymers. The isoidide-based diacid is a potential renewable alternative to terephthalic acid.",

keywords = "asymmetric transfer hydrogenation, molecular structure, terephthalic acid, crystal-structure, isosorbide, chemistry, polymers, ligands, polyurethanes, isomannide",

author = "J. Wu and P. Eduard and S. Thiyagarajan and {van Haveren}, J. and {van Es}, D.S. and C.E. Koning and M. Lutz and {Fonesca Guerra}, C.",

year = "2011",

doi = "10.1002/cssc.201100076",

language = "English",

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T1 - Isohexide Derivatives from Renewable Resources as Chiral Building Blocks

AU - Wu, J.

AU - Eduard, P.

AU - Thiyagarajan, S.

AU - van Haveren, J.

AU - van Es, D.S.

AU - Koning, C.E.

AU - Lutz, M.

AU - Fonesca Guerra, C.

PY - 2011

Y1 - 2011

N2 - A new family of C2/C5 carbon-extended isohexide derivatives is synthesized in a stereo-controlled manner with high purity and good yield. These chiral and rigid biobased building blocks can be widely applied: in pharmaceuticals, cholesteric liquid crystals, and as building blocks for high-performance polymers. The isoidide-based diacid is a potential renewable alternative to terephthalic acid.

AB - A new family of C2/C5 carbon-extended isohexide derivatives is synthesized in a stereo-controlled manner with high purity and good yield. These chiral and rigid biobased building blocks can be widely applied: in pharmaceuticals, cholesteric liquid crystals, and as building blocks for high-performance polymers. The isoidide-based diacid is a potential renewable alternative to terephthalic acid.

KW - asymmetric transfer hydrogenation

KW - molecular structure

KW - terephthalic acid

KW - crystal-structure

KW - isosorbide

KW - chemistry

KW - polymers

KW - ligands

KW - polyurethanes

KW - isomannide

U2 - 10.1002/cssc.201100076

DO - 10.1002/cssc.201100076

M3 - Article

VL - 4

SP - 599

EP - 603

JO - ChemSusChem

JF - ChemSusChem

SN - 1864-5631

IS - 5

ER -