Intercomparison of measurements of NO2 concentrations in the atmosphere simulation chamber SAPHIR during the NO3Comp campaign

H. Fuchs, S.M. Ball, B. Bohn, T. Brauers, R.C. Cohen, H.P. Dorn, W.P. Dubé, J.L. Fry, R. Häseler, U. Heitmann, R.L. Jones, J. Kleffmann, T.F. Mentel, P. Müsgen, F. Rohrer, A.W. Rollins, A.A. Ruth, A. Kiendler-Scharr, E. Schlosser, A.J.L. ShillingsR. Tillmann, R.M. Varma, D.S. Venables, G. Villena Tapia, A. Wahner, R. Wegener, P.J. Wooldridge, S.S. Brown

Research output: Contribution to journalArticleAcademicpeer-review

53 Citations (Scopus)

Abstract

NO2 concentrations were measured by various instruments during the NO3Comp campaign at the atmosphere simulation chamber SAPHIR at Forschungszentrum Jülich, Germany, in June 2007. Analytical methods included photolytic conversion with chemiluminescence (PC-CLD), broadband cavity ring-down spectroscopy (BBCRDS), pulsed cavity ring-down spectroscopy (CRDS), incoherent broadband cavity-enhanced absorption spectroscopy (IBB\-CEAS), and laser-induced fluorescence (LIF). All broadband absorption spectrometers were optimized for the detection of the main target species of the campaign, NO3, but were also capable of detecting NO2 simultaneously with reduced sensitivity. NO2 mixing ratios in the chamber were within a range characteristic of polluted, urban conditions, with a maximum mixing ratio of approximately 75 ppbv. The overall agreement between measurements of all instruments was excellent. Linear fits of the combined data sets resulted in slopes that differ from unity only within the stated uncertainty of each instrument. Possible interferences from species such as water vapor and ozone were negligible under the experimental conditions.
Original languageEnglish
Pages (from-to)21-37
Number of pages17
JournalAtmospheric Measurement Techniques
Volume3
Issue number1
DOIs
Publication statusPublished - 2010
Externally publishedYes

Fingerprint

Dive into the research topics of 'Intercomparison of measurements of NO2 concentrations in the atmosphere simulation chamber SAPHIR during the NO3Comp campaign'. Together they form a unique fingerprint.

Cite this