Influence of calcium and phosphate on pH dependency of arsenite and arsenate adsorption to goethite

Yingxuan Deng, Yongtao Li, Xiaojing Li, Yang Sun, Jie Ma, Mei Lei, Liping Weng*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

10 Citations (Scopus)

Abstract

In the environment, simultaneous presence of arsenic (As) of different oxidation states is common, which hampers our understanding of As behavior. In the current study, the pH dependency of arsenite (As(III)) and arsenate (As(V)) adsorption to goethite under the influence of calcium (Ca2+) (as a major cation) and phosphate (PO4 3−) (as a major anion) was studied, and the reliability of the CD-MUSIC model prediction was tested. The results show that the presence of the major ions led in general to a weaker and more complicated pH dependency of As adsorption. Calcium promoted As(V) adsorption especially at high pH, which can reverse the direction of the pH dependency. The presence of Ca2+ can even decrease As(III) adsorption when As(V) and/or PO4 3− are present. Phosphate competed strongly with both As(III) and As(V) in their adsorption, especially at intermediate and low pH. In the multi-component system, As(III) adsorbs weaker than As(V) over the environmental relevant pH range, therefore it is often the dominant As species in solution and soluble As(III) concentration generally decreases with increasing pH. In the same pH range, As(V) adsorption shows a complicated pH dependency. Soluble As(V) reaches a minimum around pH 6 at high concentration of major bivalent cations (e.g. Ca2+), whereas soluble As(V) will decrease with pH at low bivalent cation concentrations. The experimental results can be reliably predicted and explained with the CD-MUSIC model. The outcome of this study can provide understanding needed in the risk assessment and remediation of As contaminated soils and water.
Original languageEnglish
Pages (from-to)617-624
JournalChemosphere
Volume199
DOIs
Publication statusPublished - 1 May 2018

Fingerprint

arsenite
Arsenic
arsenate
goethite
Adsorption
Calcium
arsenic
Phosphates
calcium
phosphate
adsorption
arsenic acid
calcium phosphate
Cations
cation
Positive ions

Keywords

  • Adsorption
  • Arsenic
  • CD-MUSIC
  • Modeling
  • Multi-component

Cite this

Deng, Yingxuan ; Li, Yongtao ; Li, Xiaojing ; Sun, Yang ; Ma, Jie ; Lei, Mei ; Weng, Liping. / Influence of calcium and phosphate on pH dependency of arsenite and arsenate adsorption to goethite. In: Chemosphere. 2018 ; Vol. 199. pp. 617-624.
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abstract = "In the environment, simultaneous presence of arsenic (As) of different oxidation states is common, which hampers our understanding of As behavior. In the current study, the pH dependency of arsenite (As(III)) and arsenate (As(V)) adsorption to goethite under the influence of calcium (Ca2+) (as a major cation) and phosphate (PO4 3−) (as a major anion) was studied, and the reliability of the CD-MUSIC model prediction was tested. The results show that the presence of the major ions led in general to a weaker and more complicated pH dependency of As adsorption. Calcium promoted As(V) adsorption especially at high pH, which can reverse the direction of the pH dependency. The presence of Ca2+ can even decrease As(III) adsorption when As(V) and/or PO4 3− are present. Phosphate competed strongly with both As(III) and As(V) in their adsorption, especially at intermediate and low pH. In the multi-component system, As(III) adsorbs weaker than As(V) over the environmental relevant pH range, therefore it is often the dominant As species in solution and soluble As(III) concentration generally decreases with increasing pH. In the same pH range, As(V) adsorption shows a complicated pH dependency. Soluble As(V) reaches a minimum around pH 6 at high concentration of major bivalent cations (e.g. Ca2+), whereas soluble As(V) will decrease with pH at low bivalent cation concentrations. The experimental results can be reliably predicted and explained with the CD-MUSIC model. The outcome of this study can provide understanding needed in the risk assessment and remediation of As contaminated soils and water.",
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Influence of calcium and phosphate on pH dependency of arsenite and arsenate adsorption to goethite. / Deng, Yingxuan; Li, Yongtao; Li, Xiaojing; Sun, Yang; Ma, Jie; Lei, Mei; Weng, Liping.

In: Chemosphere, Vol. 199, 01.05.2018, p. 617-624.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Influence of calcium and phosphate on pH dependency of arsenite and arsenate adsorption to goethite

AU - Deng, Yingxuan

AU - Li, Yongtao

AU - Li, Xiaojing

AU - Sun, Yang

AU - Ma, Jie

AU - Lei, Mei

AU - Weng, Liping

PY - 2018/5/1

Y1 - 2018/5/1

N2 - In the environment, simultaneous presence of arsenic (As) of different oxidation states is common, which hampers our understanding of As behavior. In the current study, the pH dependency of arsenite (As(III)) and arsenate (As(V)) adsorption to goethite under the influence of calcium (Ca2+) (as a major cation) and phosphate (PO4 3−) (as a major anion) was studied, and the reliability of the CD-MUSIC model prediction was tested. The results show that the presence of the major ions led in general to a weaker and more complicated pH dependency of As adsorption. Calcium promoted As(V) adsorption especially at high pH, which can reverse the direction of the pH dependency. The presence of Ca2+ can even decrease As(III) adsorption when As(V) and/or PO4 3− are present. Phosphate competed strongly with both As(III) and As(V) in their adsorption, especially at intermediate and low pH. In the multi-component system, As(III) adsorbs weaker than As(V) over the environmental relevant pH range, therefore it is often the dominant As species in solution and soluble As(III) concentration generally decreases with increasing pH. In the same pH range, As(V) adsorption shows a complicated pH dependency. Soluble As(V) reaches a minimum around pH 6 at high concentration of major bivalent cations (e.g. Ca2+), whereas soluble As(V) will decrease with pH at low bivalent cation concentrations. The experimental results can be reliably predicted and explained with the CD-MUSIC model. The outcome of this study can provide understanding needed in the risk assessment and remediation of As contaminated soils and water.

AB - In the environment, simultaneous presence of arsenic (As) of different oxidation states is common, which hampers our understanding of As behavior. In the current study, the pH dependency of arsenite (As(III)) and arsenate (As(V)) adsorption to goethite under the influence of calcium (Ca2+) (as a major cation) and phosphate (PO4 3−) (as a major anion) was studied, and the reliability of the CD-MUSIC model prediction was tested. The results show that the presence of the major ions led in general to a weaker and more complicated pH dependency of As adsorption. Calcium promoted As(V) adsorption especially at high pH, which can reverse the direction of the pH dependency. The presence of Ca2+ can even decrease As(III) adsorption when As(V) and/or PO4 3− are present. Phosphate competed strongly with both As(III) and As(V) in their adsorption, especially at intermediate and low pH. In the multi-component system, As(III) adsorbs weaker than As(V) over the environmental relevant pH range, therefore it is often the dominant As species in solution and soluble As(III) concentration generally decreases with increasing pH. In the same pH range, As(V) adsorption shows a complicated pH dependency. Soluble As(V) reaches a minimum around pH 6 at high concentration of major bivalent cations (e.g. Ca2+), whereas soluble As(V) will decrease with pH at low bivalent cation concentrations. The experimental results can be reliably predicted and explained with the CD-MUSIC model. The outcome of this study can provide understanding needed in the risk assessment and remediation of As contaminated soils and water.

KW - Adsorption

KW - Arsenic

KW - CD-MUSIC

KW - Modeling

KW - Multi-component

U2 - 10.1016/j.chemosphere.2018.02.018

DO - 10.1016/j.chemosphere.2018.02.018

M3 - Article

VL - 199

SP - 617

EP - 624

JO - Chemosphere

JF - Chemosphere

SN - 0045-6535

ER -