Highly selective recovery of medium chain carboxylates from co-fermented organic wastes using anion exchange with carbon dioxide expanded methanol desorption

Clara Fernando-Foncillas; Carlos I. Cabrera-Rodríguez; Francisco Caparrós-Salvador; Cristiano Varrone; Adrie J.J. Straathof

doi:10.1016/j.biortech.2020.124178

Highly selective recovery of medium chain carboxylates from co-fermented organic wastes using anion exchange with carbon dioxide expanded methanol desorption

Clara Fernando-Foncillas, Carlos I. Cabrera-Rodríguez, Francisco Caparrós-Salvador, Cristiano Varrone, Adrie J.J. Straathof^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

26 Citations (Scopus)

Abstract

The aim of this work was to recover a mixture of carboxylates ranging from 2 to 7 carbon atoms using a strong anion exchange resin, followed by desorption with CO₂-expanded methanol. Medium chain carboxylates hexanoate and heptanoate adsorbed better than acetate, and the corresponding medium chain carboxylic acids desorbed easier than acetic acid. Consequently, hexanoate and heptanoate were concentrated up to 14.6 and 20.7 times, respectively. These findings will enable effective separation and purification of the produced carboxylic acids. Notably, the presence of inorganic ions in the sample, such as chloride, decreased the adsorption affinity compared to a synthetic mixture only of carboxylates.

Original language	English
Article number	124178
Journal	Bioresource Technology
Volume	319
Early online date	29 Sept 2020
DOIs	https://doi.org/10.1016/j.biortech.2020.124178
Publication status	Published - Jan 2021

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Anion exchange chromatography
Co-fermentation of organic wastes
CO-expanded methanol
Hexanoic acid
Medium chain carboxylic acids

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10.1016/j.biortech.2020.124178Licence: CC BY

https://edepot.wur.nl/533084Licence: CC BY

Cite this

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title = "Highly selective recovery of medium chain carboxylates from co-fermented organic wastes using anion exchange with carbon dioxide expanded methanol desorption",

abstract = "The aim of this work was to recover a mixture of carboxylates ranging from 2 to 7 carbon atoms using a strong anion exchange resin, followed by desorption with CO2-expanded methanol. Medium chain carboxylates hexanoate and heptanoate adsorbed better than acetate, and the corresponding medium chain carboxylic acids desorbed easier than acetic acid. Consequently, hexanoate and heptanoate were concentrated up to 14.6 and 20.7 times, respectively. These findings will enable effective separation and purification of the produced carboxylic acids. Notably, the presence of inorganic ions in the sample, such as chloride, decreased the adsorption affinity compared to a synthetic mixture only of carboxylates.",

keywords = "Anion exchange chromatography, Co-fermentation of organic wastes, CO-expanded methanol, Hexanoic acid, Medium chain carboxylic acids",

author = "Clara Fernando-Foncillas and Cabrera-Rodr{\'i}guez, \{Carlos I.\} and Francisco Caparr{\'o}s-Salvador and Cristiano Varrone and Straathof, \{Adrie J.J.\}",

year = "2021",

month = jan,

doi = "10.1016/j.biortech.2020.124178",

language = "English",

volume = "319",

journal = "Bioresource Technology",

issn = "0960-8524",

publisher = "Elsevier",

}

Highly selective recovery of medium chain carboxylates from co-fermented organic wastes using anion exchange with carbon dioxide expanded methanol desorption. / Fernando-Foncillas, Clara; Cabrera-Rodríguez, Carlos I.; Caparrós-Salvador, Francisco et al.
In: Bioresource Technology, Vol. 319, 124178, 01.2021.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Highly selective recovery of medium chain carboxylates from co-fermented organic wastes using anion exchange with carbon dioxide expanded methanol desorption

AU - Fernando-Foncillas, Clara

AU - Cabrera-Rodríguez, Carlos I.

AU - Caparrós-Salvador, Francisco

AU - Varrone, Cristiano

AU - Straathof, Adrie J.J.

PY - 2021/1

Y1 - 2021/1

N2 - The aim of this work was to recover a mixture of carboxylates ranging from 2 to 7 carbon atoms using a strong anion exchange resin, followed by desorption with CO2-expanded methanol. Medium chain carboxylates hexanoate and heptanoate adsorbed better than acetate, and the corresponding medium chain carboxylic acids desorbed easier than acetic acid. Consequently, hexanoate and heptanoate were concentrated up to 14.6 and 20.7 times, respectively. These findings will enable effective separation and purification of the produced carboxylic acids. Notably, the presence of inorganic ions in the sample, such as chloride, decreased the adsorption affinity compared to a synthetic mixture only of carboxylates.

AB - The aim of this work was to recover a mixture of carboxylates ranging from 2 to 7 carbon atoms using a strong anion exchange resin, followed by desorption with CO2-expanded methanol. Medium chain carboxylates hexanoate and heptanoate adsorbed better than acetate, and the corresponding medium chain carboxylic acids desorbed easier than acetic acid. Consequently, hexanoate and heptanoate were concentrated up to 14.6 and 20.7 times, respectively. These findings will enable effective separation and purification of the produced carboxylic acids. Notably, the presence of inorganic ions in the sample, such as chloride, decreased the adsorption affinity compared to a synthetic mixture only of carboxylates.

KW - Anion exchange chromatography

KW - Co-fermentation of organic wastes

KW - CO-expanded methanol

KW - Hexanoic acid

KW - Medium chain carboxylic acids

U2 - 10.1016/j.biortech.2020.124178

DO - 10.1016/j.biortech.2020.124178

M3 - Article

AN - SCOPUS:85092216500

SN - 0960-8524

VL - 319

JO - Bioresource Technology

JF - Bioresource Technology

M1 - 124178

ER -

Highly selective recovery of medium chain carboxylates from co-fermented organic wastes using anion exchange with carbon dioxide expanded methanol desorption

Abstract

UN SDGs

Keywords

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