Formation of binuclear pyrazolate-bridged palladium carboxylates in the reactions of [Pd(Hdmpz)4](OOCR2) (R = Me, Bu t, Ph) with heterometallic Pd-Co acetate

E.V. Perova, F.M. Miloserdov, M. Yakovleva, S.E. Nefedov

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Abstract

The reactions of [Pd(Hdmpz)4](OOCR)2 (R = Me, Bu t, Ph, Hdmpz = 3,5-dimethylpyrazole) with the heterometallic acetate Pd(μ-OOCMe)4Co(NCMe) gives pyrazolate-bridged dimers Pd 2(μ-dmpz)2(Hdmpz)2(OOCR)2 (R = Me, Bu t, Ph), which were characterized by X-ray diffraction

Original languageEnglish
Pages (from-to)1590-1602
Number of pages13
JournalRussian Journal of Inorganic Chemistry
Volume54
Issue number10
DOIs
Publication statusPublished - Oct 2009
Externally publishedYes

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