Effect of the nature of carboxylate anion on the features of intramolecular hydrogen bonding in [Pd(Hdmpz)4](OOCR)2 (R = Me, Bu t, Ph)

E.V. Perova; F.M. Miloserdov; M.A. Yakovleva; I.P. Stolyarov; S.E. Nefedov

doi:10.1134/S0036023609090071

Effect of the nature of carboxylate anion on the features of intramolecular hydrogen bonding in [Pd(Hdmpz)₄](OOCR)₂ (R = Me, Bu ^t, Ph)

E.V. Perova, F.M. Miloserdov, M.A. Yakovleva, I.P. Stolyarov, S.E. Nefedov

Research output: Contribution to journal › Article › Academic › peer-review

3 Citations (Scopus)

Abstract

We discovered that reactions of [Pd(OOCMe)₂] _n and Pd₃(μ-OOCMe) with 3,5-dimethylpyrazole (Hdmpz) yield mononuclear complex [Pd(Hdmpz)₄](OOCMe)₂, in which acetate anions can exchange for pivalate or benzoate anions in reactions with proper acids. The specifics of intramolecular hydrogen bonding in the complexes prepared are discussed as dependent on the nature of the carboxylate anion using X-ray crystallography data.

Original language	English
Pages (from-to)	1378-1389
Number of pages	12
Journal	Russian Journal of Inorganic Chemistry
Volume	54
Issue number	9
DOIs	https://doi.org/10.1134/S0036023609090071
Publication status	Published - Sept 2009
Externally published	Yes

Access to Document

10.1134/S0036023609090071

Cite this

@article{508b88dcfa0642a49e1bc1ea95cf1124,

title = "Effect of the nature of carboxylate anion on the features of intramolecular hydrogen bonding in [Pd(Hdmpz)4](OOCR)2 (R = Me, Bu t, Ph)",

abstract = "We discovered that reactions of [Pd(OOCMe)2] n and Pd3(μ-OOCMe) with 3,5-dimethylpyrazole (Hdmpz) yield mononuclear complex [Pd(Hdmpz)4](OOCMe)2, in which acetate anions can exchange for pivalate or benzoate anions in reactions with proper acids. The specifics of intramolecular hydrogen bonding in the complexes prepared are discussed as dependent on the nature of the carboxylate anion using X-ray crystallography data.",

author = "E.V. Perova and F.M. Miloserdov and M.A. Yakovleva and I.P. Stolyarov and S.E. Nefedov",

year = "2009",

month = sep,

doi = "10.1134/S0036023609090071",

language = "English",

volume = "54",

pages = "1378--1389",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Pleiades Publishing",

number = "9",

}

TY - JOUR

T1 - Effect of the nature of carboxylate anion on the features of intramolecular hydrogen bonding in [Pd(Hdmpz)4](OOCR)2 (R = Me, Bu t, Ph)

AU - Perova, E.V.

AU - Miloserdov, F.M.

AU - Yakovleva, M.A.

AU - Stolyarov, I.P.

AU - Nefedov, S.E.

PY - 2009/9

Y1 - 2009/9

N2 - We discovered that reactions of [Pd(OOCMe)2] n and Pd3(μ-OOCMe) with 3,5-dimethylpyrazole (Hdmpz) yield mononuclear complex [Pd(Hdmpz)4](OOCMe)2, in which acetate anions can exchange for pivalate or benzoate anions in reactions with proper acids. The specifics of intramolecular hydrogen bonding in the complexes prepared are discussed as dependent on the nature of the carboxylate anion using X-ray crystallography data.

AB - We discovered that reactions of [Pd(OOCMe)2] n and Pd3(μ-OOCMe) with 3,5-dimethylpyrazole (Hdmpz) yield mononuclear complex [Pd(Hdmpz)4](OOCMe)2, in which acetate anions can exchange for pivalate or benzoate anions in reactions with proper acids. The specifics of intramolecular hydrogen bonding in the complexes prepared are discussed as dependent on the nature of the carboxylate anion using X-ray crystallography data.

U2 - 10.1134/S0036023609090071

DO - 10.1134/S0036023609090071

M3 - Article

AN - SCOPUS:70349193551

SN - 0036-0236

VL - 54

SP - 1378

EP - 1389

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 9

ER -

Effect of the nature of carboxylate anion on the features of intramolecular hydrogen bonding in [Pd(Hdmpz)4](OOCR)2 (R = Me, Bu t, Ph)

Abstract

Access to Document

Fingerprint

Cite this

Effect of the nature of carboxylate anion on the features of intramolecular hydrogen bonding in [Pd(Hdmpz)₄](OOCR)₂ (R = Me, Bu ^t, Ph)