Deazaflavins as photocatalysts for the direct reductive regeneration of flavoenzymes

M.M.C.H. van Schie, S.H.H. Younes, M.C.R. Rauch, M. Pesic, C.E. Paul, I.W.C.E. Arends, F. Hollmann*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

7 Citations (Scopus)

Abstract

Deazaflavins are potentially useful redox mediators for the direct, nicotinamide-independent regeneration of oxidoreductases. Especially the O2-stability of their reduced forms have attracted significant interest for the regeneration of monooxygenases. In this contribution we further investigate the photochemical properties of deazaflavins and investigate the scope and limitations of deazaflavin-based photoenzymatic reaction systems.
Original languageEnglish
Pages (from-to)277-283
JournalMolecular Catalysis
Volume452
DOIs
Publication statusPublished - 1 Jun 2018

Keywords

  • Biocatalysis
  • Flavin
  • Old yellow enzyme
  • Oxygen dilemma
  • Photochemistry

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    van Schie, M. M. C. H., Younes, S. H. H., Rauch, M. C. R., Pesic, M., Paul, C. E., Arends, I. W. C. E., & Hollmann, F. (2018). Deazaflavins as photocatalysts for the direct reductive regeneration of flavoenzymes. Molecular Catalysis, 452, 277-283. https://doi.org/10.1016/j.mcat.2018.04.015