Co- and Terpolyesters based on isosorbide and succinic acid for coating applications : synthesis and characterization

B.A.J. Noordover; V.G. van Staalduinen; R. Duchateau; C.E. Koning; R.A.T.M. van Benthem; M. Mak; A. Heise; A.E. Frissen; J. van Haveren

doi:10.1021/bm060713v

Co- and Terpolyesters based on isosorbide and succinic acid for coating applications : synthesis and characterization

B.A.J. Noordover, V.G. van Staalduinen, R. Duchateau, C.E. Koning, R.A.T.M. van Benthem, M. Mak, A. Heise, A.E. Frissen, J. van Haveren

Research output: Contribution to journal › Article › Academic › peer-review

202 Citations (Scopus)

Abstract

Co- and terpolyesters based on succinic acid and isosorbide in combination with other renewable monomers such as 2,3-butanediol, 1,3-propanediol, and citric acid were synthesized and characterized. Linear polyesters were obtained via melt polycondensation of nonactivated dicarboxylic acids with OH functional monomers. Polymer end functionality (i.e., hydroxyl or carboxylic acid) was controlled by adjusting the monomer stoichiometry. The glass transition temperatures of the resulting polyesters could be effectively adjusted by varying the polymer composition and molar mass. By adding polyfunctional monomers such as trimethylolpropane or citric acid, polyesters with enhanced functionality were obtained. These biobased polyesters displayed functionalities and Tg values in the appropriate range for (powder) coating applications. The polyesters were cross-linked using conventional curing agents. Coatings from branched polyesters-hydroxyl as well as acid functional-showed significantly improved mechanical and chemical resistance compared to those formulated from linear polymers. These renewable polyesters proved to be suitable materials for coating applications with respect to solvent resistance, impact resistance, and hardness.

Original language	English
Pages (from-to)	3406-3416
Journal	Biomacromolecules
Volume	7
Issue number	12
DOIs	https://doi.org/10.1021/bm060713v
Publication status	Published - 2006

Keywords

end-groups
polyesters
esterification
poly(ethylene-terephthalate)
1,4/3,6-dianhydro-d-glucitol
1,4-3,6-dianhydrosorbitol
blends
uv

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/bm060713v

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title = "Co- and Terpolyesters based on isosorbide and succinic acid for coating applications : synthesis and characterization",

abstract = "Co- and terpolyesters based on succinic acid and isosorbide in combination with other renewable monomers such as 2,3-butanediol, 1,3-propanediol, and citric acid were synthesized and characterized. Linear polyesters were obtained via melt polycondensation of nonactivated dicarboxylic acids with OH functional monomers. Polymer end functionality (i.e., hydroxyl or carboxylic acid) was controlled by adjusting the monomer stoichiometry. The glass transition temperatures of the resulting polyesters could be effectively adjusted by varying the polymer composition and molar mass. By adding polyfunctional monomers such as trimethylolpropane or citric acid, polyesters with enhanced functionality were obtained. These biobased polyesters displayed functionalities and Tg values in the appropriate range for (powder) coating applications. The polyesters were cross-linked using conventional curing agents. Coatings from branched polyesters-hydroxyl as well as acid functional-showed significantly improved mechanical and chemical resistance compared to those formulated from linear polymers. These renewable polyesters proved to be suitable materials for coating applications with respect to solvent resistance, impact resistance, and hardness.",

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author = "B.A.J. Noordover and {van Staalduinen}, V.G. and R. Duchateau and C.E. Koning and {van Benthem}, R.A.T.M. and M. Mak and A. Heise and A.E. Frissen and {van Haveren}, J.",

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doi = "10.1021/bm060713v",

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TY - JOUR

T1 - Co- and Terpolyesters based on isosorbide and succinic acid for coating applications : synthesis and characterization

AU - Noordover, B.A.J.

AU - van Staalduinen, V.G.

AU - Duchateau, R.

AU - Koning, C.E.

AU - van Benthem, R.A.T.M.

AU - Mak, M.

AU - Heise, A.

AU - Frissen, A.E.

AU - van Haveren, J.

PY - 2006

Y1 - 2006

N2 - Co- and terpolyesters based on succinic acid and isosorbide in combination with other renewable monomers such as 2,3-butanediol, 1,3-propanediol, and citric acid were synthesized and characterized. Linear polyesters were obtained via melt polycondensation of nonactivated dicarboxylic acids with OH functional monomers. Polymer end functionality (i.e., hydroxyl or carboxylic acid) was controlled by adjusting the monomer stoichiometry. The glass transition temperatures of the resulting polyesters could be effectively adjusted by varying the polymer composition and molar mass. By adding polyfunctional monomers such as trimethylolpropane or citric acid, polyesters with enhanced functionality were obtained. These biobased polyesters displayed functionalities and Tg values in the appropriate range for (powder) coating applications. The polyesters were cross-linked using conventional curing agents. Coatings from branched polyesters-hydroxyl as well as acid functional-showed significantly improved mechanical and chemical resistance compared to those formulated from linear polymers. These renewable polyesters proved to be suitable materials for coating applications with respect to solvent resistance, impact resistance, and hardness.

AB - Co- and terpolyesters based on succinic acid and isosorbide in combination with other renewable monomers such as 2,3-butanediol, 1,3-propanediol, and citric acid were synthesized and characterized. Linear polyesters were obtained via melt polycondensation of nonactivated dicarboxylic acids with OH functional monomers. Polymer end functionality (i.e., hydroxyl or carboxylic acid) was controlled by adjusting the monomer stoichiometry. The glass transition temperatures of the resulting polyesters could be effectively adjusted by varying the polymer composition and molar mass. By adding polyfunctional monomers such as trimethylolpropane or citric acid, polyesters with enhanced functionality were obtained. These biobased polyesters displayed functionalities and Tg values in the appropriate range for (powder) coating applications. The polyesters were cross-linked using conventional curing agents. Coatings from branched polyesters-hydroxyl as well as acid functional-showed significantly improved mechanical and chemical resistance compared to those formulated from linear polymers. These renewable polyesters proved to be suitable materials for coating applications with respect to solvent resistance, impact resistance, and hardness.

KW - end-groups

KW - polyesters

KW - esterification

KW - poly(ethylene-terephthalate)

KW - 1,4/3,6-dianhydro-d-glucitol

KW - 1,4-3,6-dianhydrosorbitol

KW - blends

KW - uv

U2 - 10.1021/bm060713v

DO - 10.1021/bm060713v

M3 - Article

SN - 1525-7797

VL - 7

SP - 3406

EP - 3416

JO - Biomacromolecules

JF - Biomacromolecules

IS - 12

ER -

Co- and Terpolyesters based on isosorbide and succinic acid for coating applications : synthesis and characterization

Abstract

Keywords

UN SDGs

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