Chromium-incorporated TUD-1 as a new visible light-sensitive photo-catalyst for selective oxidation of propane

M.S. Hamdy Mohamed Saad; O. Berg; J.C. Jansen; T. Maschmeyer; A. Arafat; J.A. Moulijn; G. Mul

doi:10.1016/j.cattod.2006.05.058

Chromium-incorporated TUD-1 as a new visible light-sensitive photo-catalyst for selective oxidation of propane

M.S. Hamdy Mohamed Saad, O. Berg, J.C. Jansen, T. Maschmeyer, A. Arafat, J.A. Moulijn, G. Mul

Research output: Contribution to journal › Article › Academic › peer-review

23 Citations (Scopus)

Abstract

Chromium was incorporated in the framework of TUD-1 mesoporous silica by a one-pot synthesis procedure, using triethanolamine as a bi-functional template. The Cr-TUD-1 catalyst was characterized by means of X-ray diffraction, high-resolution transmission electron microscopy, UV¿vis and Raman spectroscopy, as well as elemental analysis and N2 sorption measurements. The results indicate that chromium is incorporated as tetrahedrally co-ordinated Cr6+ in the framework of TUD-1. When tested as a catalyst for the photo-oxidation of propane, Cr-TUD-1 showed high activity and high selectivity towards acetone under visible light irradiation (¿ = 435 nm).

Original language	English
Pages (from-to)	337-342
Journal	Catalysis today
Volume	117
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cattod.2006.05.058
Publication status	Published - 2006

Keywords

containing mesoporous silica
metal-oxide surfaces
photocatalytic reaction
irradiation
combustion
no
dehydrogenation
hydrocarbons
reduction
zeolite

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10.1016/j.cattod.2006.05.058

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title = "Chromium-incorporated TUD-1 as a new visible light-sensitive photo-catalyst for selective oxidation of propane",

abstract = "Chromium was incorporated in the framework of TUD-1 mesoporous silica by a one-pot synthesis procedure, using triethanolamine as a bi-functional template. The Cr-TUD-1 catalyst was characterized by means of X-ray diffraction, high-resolution transmission electron microscopy, UV¿vis and Raman spectroscopy, as well as elemental analysis and N2 sorption measurements. The results indicate that chromium is incorporated as tetrahedrally co-ordinated Cr6+ in the framework of TUD-1. When tested as a catalyst for the photo-oxidation of propane, Cr-TUD-1 showed high activity and high selectivity towards acetone under visible light irradiation (¿ = 435 nm).",

keywords = "containing mesoporous silica, metal-oxide surfaces, photocatalytic reaction, irradiation, combustion, no, dehydrogenation, hydrocarbons, reduction, zeolite",

author = "{Hamdy Mohamed Saad}, M.S. and O. Berg and J.C. Jansen and T. Maschmeyer and A. Arafat and J.A. Moulijn and G. Mul",

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year = "2006",

doi = "10.1016/j.cattod.2006.05.058",

language = "English",

volume = "117",

pages = "337--342",

journal = "Catalysis today",

issn = "0920-5861",

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number = "1-3",

}

TY - JOUR

T1 - Chromium-incorporated TUD-1 as a new visible light-sensitive photo-catalyst for selective oxidation of propane

AU - Hamdy Mohamed Saad, M.S.

AU - Berg, O.

AU - Jansen, J.C.

AU - Maschmeyer, T.

AU - Arafat, A.

AU - Moulijn, J.A.

AU - Mul, G.

N1 - 000240652000053

PY - 2006

Y1 - 2006

N2 - Chromium was incorporated in the framework of TUD-1 mesoporous silica by a one-pot synthesis procedure, using triethanolamine as a bi-functional template. The Cr-TUD-1 catalyst was characterized by means of X-ray diffraction, high-resolution transmission electron microscopy, UV¿vis and Raman spectroscopy, as well as elemental analysis and N2 sorption measurements. The results indicate that chromium is incorporated as tetrahedrally co-ordinated Cr6+ in the framework of TUD-1. When tested as a catalyst for the photo-oxidation of propane, Cr-TUD-1 showed high activity and high selectivity towards acetone under visible light irradiation (¿ = 435 nm).

AB - Chromium was incorporated in the framework of TUD-1 mesoporous silica by a one-pot synthesis procedure, using triethanolamine as a bi-functional template. The Cr-TUD-1 catalyst was characterized by means of X-ray diffraction, high-resolution transmission electron microscopy, UV¿vis and Raman spectroscopy, as well as elemental analysis and N2 sorption measurements. The results indicate that chromium is incorporated as tetrahedrally co-ordinated Cr6+ in the framework of TUD-1. When tested as a catalyst for the photo-oxidation of propane, Cr-TUD-1 showed high activity and high selectivity towards acetone under visible light irradiation (¿ = 435 nm).

KW - containing mesoporous silica

KW - metal-oxide surfaces

KW - photocatalytic reaction

KW - irradiation

KW - combustion

KW - no

KW - dehydrogenation

KW - hydrocarbons

KW - reduction

KW - zeolite

U2 - 10.1016/j.cattod.2006.05.058

DO - 10.1016/j.cattod.2006.05.058

M3 - Article

SN - 0920-5861

VL - 117

SP - 337

EP - 342

JO - Catalysis today

JF - Catalysis today

IS - 1-3

ER -

Chromium-incorporated TUD-1 as a new visible light-sensitive photo-catalyst for selective oxidation of propane

Abstract

Keywords

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