Approach Matters: The Kinetics of Interfacial Inverse-Electron Demand Diels-Alder Reactions

Rickdeb Sen, Digvijay Gahtory, Jorge Escorihuela, Judith Firet, Sidharam P. Pujari, Han Zuilhof*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

4 Citations (Scopus)

Abstract

Rapid and quantitative click functionalization of surfaces remains an interesting challenge in surface chemistry. In this regard, inverse electron demand Diels-Alder (IEDDA) reactions represent a promising metal-free candidate. Herein, we reveal quantitative surface functionalization within 15min. Furthermore, we report the comprehensive effects of substrate stereochemistry, surrounding microenvironment and substrate order on the reaction kinetics as obtained by surface-bound mass spectrometry (DART-HRMS).
Original languageEnglish
Pages (from-to)13015-13022
JournalChemistry-A European Journal
Volume23
Issue number53
DOIs
Publication statusPublished - 2017

Keywords

  • Cycloaddition
  • Diels-Alder reaction
  • Mass spectrometry
  • Organic surface chemistry
  • Reaction rates

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