Application of the NICADonnan model for proton, copper and uranyl binding to humic acid

T. Saito, S. Nagasaki, S. Tanaka, L.K. Koopal

Research output: Contribution to journalArticleAcademicpeer-review

29 Citations (Scopus)

Abstract

Humic acids are natural organic materials that play an important role in the migration of heavy metal and actinide ions in aquatic and soil systems. In the present study, the binding of protons, copper ions and uranyl ions to the purified Aldrich humic acid (PAHA) is investigated and the results are modeled with the Non-Ideal Competitive Adsorption (NICA) model extended with electrostatic interactions according to the Donnan model (NICA-Donnan model). The NICA part of the model enables one to describe the competitive ion binding to a heterogeneous substrate taking into account a different stoichiometry per ion. The NICA-Donnan model can describe the binding of the ions to PAHA in large concentration ranges (3
Original languageEnglish
Pages (from-to)567-574
JournalRadiochimica Acta
Volume92
Issue number9-11
DOIs
Publication statusPublished - 2004

Keywords

  • metal-ion binding
  • fulvic-acids
  • humate interactions
  • substances
  • complexation
  • adsorption
  • parameters
  • heterogeneity
  • uranium(vi)
  • goethite

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