An efficient one pot conversion of glycerol to lactic acid using bimetallic gold-platinum catalysts on a nanocrystalline CeO2 support

R.K.P. Purushothaman, J. van Haveren, D.S. van Es, I. Melian-Cabrera, J.D. Meeldijk, H.J. Heeres

Research output: Contribution to journalArticleAcademicpeer-review

157 Citations (Scopus)

Abstract

The one pot conversion of glycerol to lactic acid using monometallic Au and Pt as well as bimetallic (Au-Pt) catalysts supported on nanocrystalline CeO2 (n-CeO2) in aqueous solution in the presence of a base and oxygen was investigated. Catalytic performance of the bimetallic catalysts is considerably better than the monometallic ones and is indicative for synergistic effects. The bimetallic system shows excellent activity (TOF = 1170 h(-1) for a batchtime of 20 min) with a high selectivity (80%) to lactic acid at 99% glycerol conversion (373 K, NaOH to glycerol ratio of 4 mol/mol 5 bar oxygen). The Au-Pt/nCeO(2) catalyst was recycled 5 times in a batch set-up without a significant drop in activity and lactic acid selectivity, indicative for good catalyst stability. (C) 2013 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)92-100
JournalApplied Catalysis B-Environmental
Volume147
DOIs
Publication statusPublished - 2014

Keywords

  • liquid-phase oxidation
  • selective oxidation
  • co oxidation
  • commodity chemicals
  • hydrogenolysis
  • metal
  • au
  • pd
  • dihydroxyacetone
  • glyceraldehyde

Fingerprint

Dive into the research topics of 'An efficient one pot conversion of glycerol to lactic acid using bimetallic gold-platinum catalysts on a nanocrystalline CeO2 support'. Together they form a unique fingerprint.

Cite this