A process for the preparation of a tertiary perester

M.C. Tammer; J. Meijer; F.P. Cuperus; J.T.P. Derksen; G.F.H. Kramer

A process for the preparation of a tertiary perester

M.C. Tammer (Inventor), J. Meijer (Inventor), F.P. Cuperus (Inventor), J.T.P. Derksen (Inventor), G.F.H. Kramer (Inventor)

Research output: Patent

Abstract

The invention relates to a process for the preparation of a tertiary perester by contacting an acyl compound with a tertiary hydroperoxide in the presence of an enzyme catalyst. The acyl compound has the formula R1[C(O)OR2]n, wherein R1 is a linear or branched, saturated or unsaturated C1-C22 group, optionally containing one or more hetero atoms, R2 represents hydrogen or has the same meaning as described for R1, and n is 1-5, or a polyalcohol ester of R1C(O)OH, wherein R1 has the same meaning as described above. The tertiary hydroperoxide has the formula [HOOCR3R3]mR4, wherein R3 represents either a methyl or an ethyl group, R4 has the same meaning as described for R1, and m is 1-5.

Original language	English
Patent number	WO9905305
Priority date	25/07/97
Publication status	Published - 4 Feb 1999

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title = "A process for the preparation of a tertiary perester",

abstract = "The invention relates to a process for the preparation of a tertiary perester by contacting an acyl compound with a tertiary hydroperoxide in the presence of an enzyme catalyst. The acyl compound has the formula R1[C(O)OR2]n, wherein R1 is a linear or branched, saturated or unsaturated C1-C22 group, optionally containing one or more hetero atoms, R2 represents hydrogen or has the same meaning as described for R1, and n is 1-5, or a polyalcohol ester of R1C(O)OH, wherein R1 has the same meaning as described above. The tertiary hydroperoxide has the formula [HOOCR3R3]mR4, wherein R3 represents either a methyl or an ethyl group, R4 has the same meaning as described for R1, and m is 1-5.",

author = "M.C. Tammer and J. Meijer and F.P. Cuperus and J.T.P. Derksen and G.F.H. Kramer",

year = "1999",

month = feb,

day = "4",

language = "English",

type = "Patent",

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TY - PAT

T1 - A process for the preparation of a tertiary perester

AU - Tammer, M.C.

AU - Meijer, J.

AU - Cuperus, F.P.

AU - Derksen, J.T.P.

AU - Kramer, G.F.H.

PY - 1999/2/4

Y1 - 1999/2/4

N2 - The invention relates to a process for the preparation of a tertiary perester by contacting an acyl compound with a tertiary hydroperoxide in the presence of an enzyme catalyst. The acyl compound has the formula R1[C(O)OR2]n, wherein R1 is a linear or branched, saturated or unsaturated C1-C22 group, optionally containing one or more hetero atoms, R2 represents hydrogen or has the same meaning as described for R1, and n is 1-5, or a polyalcohol ester of R1C(O)OH, wherein R1 has the same meaning as described above. The tertiary hydroperoxide has the formula [HOOCR3R3]mR4, wherein R3 represents either a methyl or an ethyl group, R4 has the same meaning as described for R1, and m is 1-5.

AB - The invention relates to a process for the preparation of a tertiary perester by contacting an acyl compound with a tertiary hydroperoxide in the presence of an enzyme catalyst. The acyl compound has the formula R1[C(O)OR2]n, wherein R1 is a linear or branched, saturated or unsaturated C1-C22 group, optionally containing one or more hetero atoms, R2 represents hydrogen or has the same meaning as described for R1, and n is 1-5, or a polyalcohol ester of R1C(O)OH, wherein R1 has the same meaning as described above. The tertiary hydroperoxide has the formula [HOOCR3R3]mR4, wherein R3 represents either a methyl or an ethyl group, R4 has the same meaning as described for R1, and m is 1-5.

M3 - Patent

M1 - WO9905305

ER -

A process for the preparation of a tertiary perester

Abstract

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