A process for the preparation of a tertiary perester

M.C. Tammer (Inventor), J. Meijer (Inventor), F.P. Cuperus (Inventor), J.T.P. Derksen (Inventor), G.F.H. Kramer (Inventor)

    Research output: PatentOther research output

    Abstract

    The invention relates to a process for the preparation of a tertiary perester by contacting an acyl compound with a tertiary hydroperoxide in the presence of an enzyme catalyst. The acyl compound has the formula R1[C(O)OR2]n, wherein R1 is a linear or branched, saturated or unsaturated C1-C22 group, optionally containing one or more hetero atoms, R2 represents hydrogen or has the same meaning as described for R1, and n is 1-5, or a polyalcohol ester of R1C(O)OH, wherein R1 has the same meaning as described above. The tertiary hydroperoxide has the formula [HOOCR3R3]mR4, wherein R3 represents either a methyl or an ethyl group, R4 has the same meaning as described for R1, and m is 1-5.
    Original languageEnglish
    Patent numberWO9905305
    Priority date25/07/97
    Publication statusPublished - 4 Feb 1999

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    Tammer, M. C., Meijer, J., Cuperus, F. P., Derksen, J. T. P., & Kramer, G. F. H. (1999). A process for the preparation of a tertiary perester. (Patent No. WO9905305).