A luminescent supramolecular polymer based on a stiff-stilbene bridged pillar[5]arene as a Pd2+-responsive smart material

Jing Wu; Chuanyun Liang; Jianyi Zhao; Han Zuilhof; Hongxia Zhao

doi:10.1039/d4py00426d

A luminescent supramolecular polymer based on a stiff-stilbene bridged pillar[5]arene as a Pd²⁺-responsive smart material

Jing Wu, Chuanyun Liang, Jianyi Zhao, Han Zuilhof, Hongxia Zhao^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Two novel stiff stilbene bridged rim-differentiated pillar[5]arenes (bis-RD-P[5]s) were designed, synthesized and characterized. Subsequently, their binding ability and fluorescence properties with a suitable tetraphenylethylene (TPE) derivative were investigated. With the aid of supramolecular assembly-induced emission (SAIE), luminescent supramolecular nanoparticles (SN) were constructed through host-guest interactions between a bis-RD-P[5] and the TPE derivative. Interestingly, the SN showed strong aggregation-induced emission (AIE) and presented special selectivity and sensitivity for Pd²⁺; the fluorescence limit of detection of SN for Pd²⁺ is 5 × 10⁻⁷ M.

Original language	English
Pages (from-to)	2773-2779
Number of pages	7
Journal	Polymer Chemistry
Volume	15
Issue number	27
DOIs	https://doi.org/10.1039/d4py00426d
Publication status	Published - 24 Jun 2024

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title = "A luminescent supramolecular polymer based on a stiff-stilbene bridged pillar[5]arene as a Pd2+-responsive smart material",

abstract = "Two novel stiff stilbene bridged rim-differentiated pillar[5]arenes (bis-RD-P[5]s) were designed, synthesized and characterized. Subsequently, their binding ability and fluorescence properties with a suitable tetraphenylethylene (TPE) derivative were investigated. With the aid of supramolecular assembly-induced emission (SAIE), luminescent supramolecular nanoparticles (SN) were constructed through host-guest interactions between a bis-RD-P[5] and the TPE derivative. Interestingly, the SN showed strong aggregation-induced emission (AIE) and presented special selectivity and sensitivity for Pd2+; the fluorescence limit of detection of SN for Pd2+ is 5 × 10−7 M.",

author = "Jing Wu and Chuanyun Liang and Jianyi Zhao and Han Zuilhof and Hongxia Zhao",

year = "2024",

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doi = "10.1039/d4py00426d",

language = "English",

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T1 - A luminescent supramolecular polymer based on a stiff-stilbene bridged pillar[5]arene as a Pd2+-responsive smart material

AU - Wu, Jing

AU - Liang, Chuanyun

AU - Zhao, Jianyi

AU - Zuilhof, Han

AU - Zhao, Hongxia

PY - 2024/6/24

Y1 - 2024/6/24

N2 - Two novel stiff stilbene bridged rim-differentiated pillar[5]arenes (bis-RD-P[5]s) were designed, synthesized and characterized. Subsequently, their binding ability and fluorescence properties with a suitable tetraphenylethylene (TPE) derivative were investigated. With the aid of supramolecular assembly-induced emission (SAIE), luminescent supramolecular nanoparticles (SN) were constructed through host-guest interactions between a bis-RD-P[5] and the TPE derivative. Interestingly, the SN showed strong aggregation-induced emission (AIE) and presented special selectivity and sensitivity for Pd2+; the fluorescence limit of detection of SN for Pd2+ is 5 × 10−7 M.

AB - Two novel stiff stilbene bridged rim-differentiated pillar[5]arenes (bis-RD-P[5]s) were designed, synthesized and characterized. Subsequently, their binding ability and fluorescence properties with a suitable tetraphenylethylene (TPE) derivative were investigated. With the aid of supramolecular assembly-induced emission (SAIE), luminescent supramolecular nanoparticles (SN) were constructed through host-guest interactions between a bis-RD-P[5] and the TPE derivative. Interestingly, the SN showed strong aggregation-induced emission (AIE) and presented special selectivity and sensitivity for Pd2+; the fluorescence limit of detection of SN for Pd2+ is 5 × 10−7 M.

U2 - 10.1039/d4py00426d

DO - 10.1039/d4py00426d

M3 - Article

AN - SCOPUS:85197871680

SN - 1759-9954

VL - 15

SP - 2773

EP - 2779

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 27

ER -

A luminescent supramolecular polymer based on a stiff-stilbene bridged pillar[5]arene as a Pd2+-responsive smart material

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A luminescent supramolecular polymer based on a stiff-stilbene bridged pillar[5]arene as a Pd²⁺-responsive smart material